Exact Rabi formula (RED) versus first-order perturbation theory (SLATE dashed). At resonance (δ/Ω = 0), PT diverges — it predicts probability > 100%.
At resonance (δ=0): Exact Rabi cycles between 0 and 1. PT gives P = (Ωt)²/4 — grows without bound. At x = 2π (one full Rabi cycle), exact P = 0, but PT predicts π² ≈ 9.87 (987%!).
Off-resonance (large δ/Ω): Both methods agree when δ/Ω ≫ 1 (weak-coupling / short-time limit). At δ/Ω = 3, curves converge.
PT validity: First-order PT requires Ωt ≪ 1 at resonance. The "perturbation is small" assumption fails when the coupling drives significant population transfer.